>First of all, thanks for the replies concerning the various reasons you are
>all constructing boards. I\ufffd\ufffdm sure I\ufffd\ufffdll find the ongoing discussions
>interesting in this group.
>
>
>
>I suppose I\ufffd\ufffdll offer something to the group by making a submission on this
>subject of Etchants. Since I don\ufffd\ufffdt know what everyone is using for
>etchants at home (and I\ufffd\ufffdm not doing any type of this work at home myself),
>I can offer what I know from the industry. My experience has been that the
>three major etchant types used are:
>
>
>
>1) Ammoniacal (Ammonium chloride)
>
>2) Cupric Chloride
>
>3) Ferric Chloride
>
>
>
>Typically I find Ammonium Chloride and Cupric Chloride used for producing
>circuit boards, and Ferric Chloride used in the chemical milling industry.
>
>
>
>For home use, I would think that either Cupric Chloride or Ferric Chloride
>would be preferred. Ammonium Chloride (as someone pointed out earlier)
>produces quite an ammonia smell, which is much worse when the solution is
>heated. However, if you are using tin / tin lead as an etch resist, then
>Ammonical Chloride is \ufffd\ufffdtypically\ufffd\ufffd required (this may not be the case in
>home etching scenarios) since other etchants will etch away tin / tin lead
>resist.
>
>
>
>Cupric Chloride and Ferric Chloride share a few similarities. In the old
>days, both were rejuvenated using the oxidizer \ufffd\ufffdchlorine gas\ufffd\ufffd, then later
>people started using Hydrogen Peroxide, but now a-days people use Sodium
>Chlorate (salt water, for example). This oxidizer can easily be made at
>home by mixing a clean rock salt with water, allowing the water to absorb
>as much salt as possible. Then the salt water (brine) is added to the
>etchant to rejuvenate it. Note\ufffd\ufffd this rejuvenation process is only for
>Cupric Chloride or Ferric Chloride\ufffd\ufffd not Ammonium Chloride. There is a
>great deal of technical detail that can be discussed when adding an
>oxidizer to the etchant (such as monitoring the oxidation reduction
>potential), but I\ufffd\ufffdm not sure if that is needed for this group. Let me
>know if you would like that information and I\ufffd\ufffdll put something together,
>or I\ufffd\ufffdm sure this information could easily be found on the Internet.
>
>
>
>Cupric Chloride and Ferric Chloride also need a certain amount of
>Hydrochloric Acid, another item fairly easily obtained (Muratic Acid can be
>used, and it is much easier to obtain). And of course, both Cupric and
>Ferric will need a certain amount of Copper and Ferric Iron ions in
>solution for the whole etching process to occur. Again, much detail is
>available for these two components (monitoring the Hcl level with methods
>such as titration or electronically, and monitoring the specific gravity of
>copper / Iron levels\ufffd\ufffd very easily done with a hydrometer).
>
>
>
>Of the three, the Ferric Chloride is probably the easiest to dispose. I
>have been told those years ago, some cities encouraged manufacturing plants
>using Ferric Chloride to dump the solution down the drain when they wanted
>to dispose of it. Apparently, it helped keep the city pipes clean! NOTE:
>(here\ufffd\ufffds my disclaimer) I am in no way suggesting that you do this with
>your ferric chloride etchant.
>
>
>
>I\ufffd\ufffdll leave it there for now. I\ufffd\ufffdll just add that I remember many years
>ago when I took an electronics class, I used Ferric Chloride as my etchant
>(just poured it out of a gallon jug and \ufffd\ufffdswished\ufffd\ufffd my board around until
>the exposed copper was gone. Worked pretty well for a single sided, single
>layer board, but I also remember that board had line widths and spaces of
>about a half inch.
>
>
>
>Thanks for letting me contribute. Take care.
>
>Marty
>
>
>
>
>
>
>
>
>
>
>
>-----Original Message-----
>From: wturchyn [mailto:wturchyn@...]
>Sent: Thursday, May 22, 2003 10:18 AM
>To: Homebrew_PCBs@yahoogroups.com
>Subject: [Homebrew_PCBs] Etchant options?
>
>
>
>A previous poster made the following comment:
> I did 'em myself using Radio Shack FeCl\ufffd\ufffd. I tried Ammonium
> Persulfate once, but NO WAY at home, ever again! Whew!
>
>I had used messy ferric chloride when I made some hobby PCBs about 25
>years ago, but I have seen other less-staining etchants are now
>available, such as ammonium persulphate and sodium persulphate.
>
>What are most people using at home, and what are the pros and
>cons of the various etchants? Cost? Shelf life? Ease of use?
>Safety? Cleanliness? Availability?
>
>WT
>Winnipeg, Canada
>
>
>
>
>
>
>
>
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