Yahoo Groups archive

Homebrew PCBs

Index last updated: 2026-04-28 23:05 UTC

Thread

Re: Copper Pennies, was First PCB.... neutralizing the HCL

Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-19 by Richard Mustakos

Dave,
Where have you been? Don't you know that we use copper plated zinc 
pennies?  And that eating a copper penny is not considered a hazard, but 
the zinc coated ones are?  I guess the acids in your stomach either 
don't dissolve copper, or it requires a lot of copper to be a problem. 
 Otherwise, lead killed the Roman Empire, but copper will have killed a 
_bunch_  of modern countries.
Does anyone know why aluminum is bad for house wiring?  (real question, 
not a joke)  Is it that aluminum has a greater thermal expansion ratio 
than copper, and so the connections worked themselves apart?
Thanks
Richard
Show quoted textHide quoted text
>But, I'm thinking that here in the US, we use copper pennies and 
>copper water pipe so we probalby dump more copper into the waste 
>stream than all the pcb houses put togehter.
>
>Dave
>  
>

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-19 by Stefan Trethan

> Does anyone know why aluminum is bad for house wiring?  (real question,
> not a joke)  Is it that aluminum has a greater thermal expansion ratio
> than copper, and so the connections worked themselves apart?
> Thanks
> Richard

aluminium forms a oxyde layer which is isolating. -> resistance -> heat ->
fire -> no more house...

using aluminium in wiring requires proper techniques when making 
connections.
if done right it is ok (e.g. power cables).

However, i know for sure they do not take any care with those aluminium
cables which hook your house to the main power cables...

it is also much more prone to breaking.

ST

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-19 by Les Newell

If I remember correctly aluminium wire will 'creep' under load so you 
lose the contact pressure. This is also a problem with solder so don't 
tin your wires if you are using screw terminals or crimps.

Les

Richard Mustakos wrote:
Show quoted textHide quoted text
> Dave,
> Where have you been? Don't you know that we use copper plated zinc 
> pennies?  And that eating a copper penny is not considered a hazard, but 
> the zinc coated ones are?  I guess the acids in your stomach either 
> don't dissolve copper, or it requires a lot of copper to be a problem. 
>  Otherwise, lead killed the Roman Empire, but copper will have killed a 
> _bunch_  of modern countries.
> Does anyone know why aluminum is bad for house wiring?  (real question, 
> not a joke)  Is it that aluminum has a greater thermal expansion ratio 
> than copper, and so the connections worked themselves apart?
> Thanks
> Richard
> 
> 
>>But, I'm thinking that here in the US, we use copper pennies and 
>>copper water pipe so we probalby dump more copper into the waste 
>>stream than all the pcb houses put togehter.
>>
>>Dave
>> 
>>
> 
> 
> 
> 
> 
> Be sure to visit the group home and check for new Bookmarks and files:
> http://groups.yahoo.com/group/Homebrew_PCBs 
> Yahoo! Groups Links
> 
> 
> 
>  
> 
>

Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-19 by leon_heller

--- In Homebrew_PCBs@yahoogroups.com, Richard Mustakos 
<rmustakos@a...> wrote:
> Dave,
> Where have you been? Don't you know that we use copper plated zinc 
> pennies? 

They are actually steel. Try a magnet on one. 8-)

Leon

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-20 by JanRwl@AOL.COM

In a message dated 5/19/2004 2:53:33 PM Central Standard Time, 
les@lnewell.screaming.net writes:
Does anyone know why aluminum is bad for house wiring?  (real question,  not 
a joke)  Is it that aluminum has a greater thermal expansion ratio than 
copper, and so the connections worked themselves apart?<<
This may CONTRIBUTE to the problem, but the MAIN reason is that aluminum 
oxidizes INSTANTLY upon contact with oxygen in the air, and then stops oxidizing 
as soon as an invisibly-thin layer of alum.oxide is created (same "chemical" as 
saphires or rubies!).   Same stuff that is used to make much sandpaper.  And 
that AlO³ is a "perfect" insulator.  So, with that working caused by the 
condition in your question, any of that which may have been scraped away and 
"contact made" upon initial installation is instantly replaced, as soon as oxygen 
touches the bare Al surface, again.  This resistance causes heat which FURTHER 
exascerbates the problem, and on it goes until the heat so generated becomes 
hot enough to melt plastic and start fires.  Now, the "heavy stuff" from the 
utility may still be aluminum, but that is fastened to the "bus" in the initial 
main breaker-panel with specially-treated connectors which (mostly-) impede 
this oxide-generation.  Thus, $Dollars are saved by using a few short feet of fat 
Al wire where copper was used decades ago.  It boggles MY tiny mind that the 
people who "thought-up the use of Al wire in house-wiring" didn't realize what 
they were DOING!  The $ speaks loudest, I guess!
                            Jan Rowland


[Non-text portions of this message have been removed]

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-20 by MaxQ

Aluminum has more resistance than copper. That's why we use copper.
Copper is a better electric conductor but more expensive. In High voltage
lines the choice is aluminum because is much cheaper than copper. And to
compensate the extra resistance they make the wires thicker. And is still
cheaper than copper. For houses copper is better because it's thinner and
the resistance is minimal.
Show quoted textHide quoted text
> > Does anyone know why aluminum is bad for house wiring?  (real question,
> > not a joke)  Is it that aluminum has a greater thermal expansion ratio
> > than copper, and so the connections worked themselves apart?
> > Thanks
> > Richard

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-20 by JanRwl@AOL.COM

In a message dated 5/19/2004 8:42:21 PM Central Standard Time, 
maxq668@... writes:
For houses copper is better because it's thinner and the resistance is 
minimal.<<

Max:  True copper is better for houses, but NOT for these reasons!  Alum. 
wire of "equivalent" resistance is only slightly larger in diameter, and, as you 
said, STILL lighter in weight.  The "size" is too close to be of importance.  
The resistance of the "Romex" made with alum. was the same as the copper.  The 
reason the copper proved the only way to go is that the Alum. FAILS after a 
short time after initial installation, as I said in a previous post.  


[Non-text portions of this message have been removed]

OT Aluminum House Wire Re: Copper Pennies, was First PCB....

2004-05-20 by Steve

We're way off topic, but I'll finish this off by explaining the
(mostly) complete reason why the use of aluminum house wiring failed
in the US.

Aluminum has a different (larger) expansion due to temp than copper
does. With the correct fixtures, it is fine and works for a long time.

However, all existing installations and existing wall sockets use
connectors with the alloy's coefficient of expansion matched to
copper. So some people were using cheaper outlets meant for copper
when they replaced or added an outlet in new construction that had all
aluminum wire. This resulted in the cycle of oxidation and heat and
subsequent fire mentioned.

Add to that, you need to size up aluminum wire a bit for the same
current as compared to copper, and people did not understand or didn't
believe it, so that would cause problems. 

Aluminum wire is perfectly safe when -all- the fixtures, outlets,
wirenuts, etc. used are made for aluminum wire. Unfortunatly a small
percentage of electricians and a large percentage of homeowners didn't
understand and mixed copper with aluminum, sometimes buying aluminum
wire to replace existing copper without swapping out the outlets and
light fixtures.

The connections made to the aluminum wire where it comes in your house
are made specifically for aluminum wire. The pressure cuts through the
oxide and makes what is called a gas-tight seal, so no further
oxidization occurs and the metals don't experience galvanic corrosion.

There, back to PCBs. ;')

Oh, yeah, current USA "copper" pennies are copper plated zinc.

Steve

OT Re: Zinc/Copper Pennies At least from Denver in 2004

2004-05-20 by ballendo

Leon,

Not sure where you got this. The last--only--(USA)steel pennies were 
made in 1943.

In 1981 they were changed to copper plated Zinc, due to a law which 
requires that the inherent metal value cannot exceed the currency 
value.

I just checked several, from 1984 to 2004(Denver minted), and none 
were attracted by the magnet.  

Ballendo



--- In Homebrew_PCBs@yahoogroups.com, "leon_heller" 
<leon_heller@h...> wrote:
> --- In Homebrew_PCBs@yahoogroups.com, Richard Mustakos 
> <rmustakos@a...> wrote:
> > Dave,
> > Where have you been? Don't you know that we use copper plated 
zinc 
Show quoted textHide quoted text
> > pennies? 
> 
> They are actually steel. Try a magnet on one. 8-)
> 
> Leon

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-20 by Stefan Trethan

> Now, the "heavy stuff" from the
> utility may still be aluminum, but that is fastened to the "bus" in the 
> initial
> main breaker-panel with specially-treated connectors which (mostly-) 
> impede
> this oxide-generation.

they use bog-standard screw terminals (big of course).
Not sure what is special about them.
I suspect the cable is no pure aluminum.


I've come across a few farmhouses having alu wiring, must have been done
around wartime, or maybe even before that.

For ligtning conductor alu is standard.
But there small gaps are no problem i guess...

ST

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-20 by JanRwl@AOL.COM

In a message dated 5/20/2004 12:48:12 AM Central Standard Time, 
stefan_trethan@... writes:
Not sure what is special about them.<< 
The ones I mean have a "grainy" (sand-like) interior with silicone grease all 
inside (to keep the Oxygen off the metal, once screwed-TIGHT).  Probably the 
PRICE is special, too!
I suspect the cable is no pure aluminum<<
It may have trace impurities, but I doubt ANY effort is made to alloy it to 
preclude this kind of electrolytic corrosion!

Bet it would be nice if alum. were easily solderable, so PCB's could be made 
with it instead of copper!  

Does anyone in here doing PCB's at home pretty-much strictly as a hobby do 
PTH?  Can this be done PRACTICALLY at home?  Then, tin-lead resist would be 
necessary for trace-etching.  How reliably could the conscientious mature 
home-tinker do tin-lead plating of a PC-pattern, and be SURE the plating did-good down 
in the holes?          Jan Rowland


[Non-text portions of this message have been removed]

Re: Copper Pennies

2004-05-20 by Alan J. Franzman

--- In Homebrew_PCBs@yahoogroups.com, "Steve" <alienrelics@y...> 
wrote:
> Oh, yeah, current USA "copper" pennies are copper plated zinc.

And lest anyone think they were pure copper before the 1982 change, 
ignoring the 1943 "wartime" steel cent, they were actually bronze
(95%copper, 5% tin and zinc) or brass (95% copper, 5% zinc)
depending on the time period - pure copper is much too soft to use 
for coins.

A.J.

OT Re: Zinc/Copper Pennies At least from Denver in 2004

2004-05-20 by leon_heller

--- In Homebrew_PCBs@yahoogroups.com, "ballendo" <ballendo@y...> 
wrote:
> Leon,
> 
> Not sure where you got this. The last--only--(USA)steel pennies 
were 
> made in 1943.
> 
> In 1981 they were changed to copper plated Zinc, due to a law which 
> requires that the inherent metal value cannot exceed the currency 
> value.
> 
> I just checked several, from 1984 to 2004(Denver minted), and none 
> were attracted by the magnet.  

I meant UK pennies, the real ones. 8-)

Leon

Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-21 by ballendo

Jan,

Check out the group links section. Markus Zingg has a VERY nice 
setup... (Worth re-creating, IMO) Down side is that he uses Bungard 
chemicals, which are not cheap to get started with. But for a 
dedicated amateur, the prices weren't TOO bad, IMO. Bungard has a USA 
rep in the northwest (chems come from Canada) I made a phone call to 
get pricing.

Another member is successfully using the blackhole technique. (I 
apologise forgetting his name just now; especially as he was very 
helpful in several private emails awhile back. Can't look it up as 
I'm not on my "normal" computer!) 

Anyways, he uses a combination of thinktink and caswell off-the-shelf 
products. He's doing small production, and reports good results.

Hope this helps,

Ballendo

--- In Homebrew_PCBs@yahoogroups.com, JanRwl@A... wrote:
> In a message dated 5/20/2004 12:48:12 AM Central Standard Time, 
> stefan_trethan@g... writes:
> Not sure what is special about them.<< 
> The ones I mean have a "grainy" (sand-like) interior with silicone 
grease all 
> inside (to keep the Oxygen off the metal, once screwed-TIGHT).  
Probably the 
> PRICE is special, too!
> I suspect the cable is no pure aluminum<<
> It may have trace impurities, but I doubt ANY effort is made to 
alloy it to 
> preclude this kind of electrolytic corrosion!
> 
> Bet it would be nice if alum. were easily solderable, so PCB's 
could be made 
> with it instead of copper!  
> 
> Does anyone in here doing PCB's at home pretty-much strictly as a 
hobby do 
> PTH?  Can this be done PRACTICALLY at home?  Then, tin-lead resist 
would be 
> necessary for trace-etching.  How reliably could the conscientious 
mature 
> home-tinker do tin-lead plating of a PC-pattern, and be SURE the 
plating did-good down 
Show quoted textHide quoted text
> in the holes?          Jan Rowland
> 
> 
> [Non-text portions of this message have been removed]

Re: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL

2004-05-21 by Jeremy Taylor

That would be me, I was going to do another long winded reply, with a  subject change, but instead I hoped the poster would search the archives a-bit. 
- also  I was going to get you those pics, but got stuck in mad scientist mode, went on vacation, came back and fried my torrodial transformer, and meters, by accidentally letting the + and - clips touch each other ... for an extended period of time. Btw torrodials smell pretty funky as they cook. 
I'm working on a new one as we speak, and I'm preparing a showcase website, with pics and stuff of my setup, which I'll toss a link to in the links section. 
IF I succeeded at cloning my self... It should be done next week, but if not, next month. 

JT
(Jeremy Taylor)
Show quoted textHide quoted text
  ----- Original Message ----- 
  From: ballendo 
  To: Homebrew_PCBs@yahoogroups.com 
  Sent: Friday, May 21, 2004 10:21 AM
  Subject: [Homebrew_PCBs] Re: Copper Pennies, was First PCB.... neutralizing the HCL


   <....>

  Another member is successfully using the blackhole technique.





[Non-text portions of this message have been removed]

Move to quarantaine

This moves the raw source file on disk only. The archive index is not changed automatically, so you still need to run a manual refresh afterward.