My experiences with Ammonium Persulphate
2004-04-09 by Phil
There was a bit of discussion about AP a while ago and now that I have had about a month of experience with it, I thought I'd report back. I had a number of misgivings about AP based on comments posted here but since I had bought it, I figured I'd use it... My set up. A vertical tank that holds 1 L, a heater that brings the temperature to 100F and a bubbler. All my boards have been double sided so there was lots of copper to etch. Issues that had been raised: - short shelf life of AP solution. I've been pouring it out of the tank and storing it in a glass jar. So far i have done 12 boards and it appears to be still quite potent after a month. The last board etched in about 13 minutes, just like the first one. I did have a huge crystal (Cu sulfate?) form in the bottom of storage jar. Kind of pretty. - toxicity/fumes. While I haven't been making cocktails with it, I can say that I've experienced no problems or skin irritation. - cost. ya got me there, its about twice the cost of FeCl Some of the benefits of AP: - clear. I can easily monitor the progress of the etch. - non-staining. I spilled a little on a wooden benchtop and some paper. neither took more of a stain than water. - the powder is not exothermic when mixing with water. FeCl is really nasty that way. (I'm sure I'm using the incorrect term here, it releases a LOT of heat when mixed with water) - I believe it has more etching capacity than FeCl. I've done twice as many boards as with my last batch of FeCl (1 L, too). This is a subjective opinion and could be completely false... - pretty blue color If I had to get some new etchant today, I think I'd experiment with HCl+H2O2 but AP is a fine etchant to use and I'm very happy with it.