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Some etched Artwork finished and questions on electrolytic etching

Some etched Artwork finished and questions on electrolytic etching

2013-09-22 by rolynd33

I recently finished some etched Pendants.
You can see sone photos here:
http://brassgoggles.co.uk/forum/index.php/topic,41175.0.html

I used the toner Transfer method and ferric chloride with good results . The etch is fairly deep compared to the usual etch depth needed for PCB but detail is still very good.

I alternatively tried the electrolytic etch method with not so much sucess. I use canon Toner and it seems it does not hold up to a copper sulfate electrolyte. Its fine in chlorides though but the saltwater etch presented its own problems, a white precipitate forms on the etched piece eating the toner. Another member suggested HP toner.
I want to try making the electrolytic etch to work, before I get myself a new/used HP printer I wanted to ask here if someone can confirm the usability of HP toner or maybe has experience with the electrolytic etch method and copper sulfate?

Re: [Homebrew_PCBs] Some etched Artwork finished and questions on electrolytic etching

2013-09-22 by Malcolm Parker-Lisberg

Did you freeze the paper after thermal transfer, or just soak in water.
Freezing for 20 mins. to 1/2 hour gives a denser transfer and easier paper removal.

Malcolm

I don't suffer from insanity I enjoy it!
Mene, mene, tekel, upharsin
The writing is on the wall.
Ha-ktovet al ha-kir

--------------------------------------------
On Sun, 9/22/13, rolynd33 <roland.rasch@...> wrote:

Subject: [Homebrew_PCBs] Some etched Artwork finished and questions on electrolytic etching
To: Homebrew_PCBs@yahoogroups.com
Date: Sunday, September 22, 2013, 11:18 AM


























I recently finished some etched Pendants.

You can see sone photos here:

http://brassgoggles.co.uk/forum/index.php/topic,41175.0.html



I used the toner Transfer method and ferric chloride with
good results . The etch is fairly deep compared to the usual
etch depth needed for PCB but detail is still very good.



I alternatively tried the electrolytic etch method with not
so much sucess. I use canon Toner and it seems it does not
hold up to a copper sulfate electrolyte. Its fine in
chlorides though but the saltwater etch presented its own
problems, a white precipitate forms on the etched piece
eating the toner. Another member suggested HP toner.

I want to try making the electrolytic etch to work, before I
get myself a new/used HP printer I wanted to ask here if
someone can confirm the usability of HP toner or maybe has
experience with the electrolytic etch method and copper
sulfate?

Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-22 by rolynd33

I use Icewater. No problems with the transfer, no pinholes etc. When I am using ferric everything works fine I only get problems when I tried electrolytic etching with copper sulfate as electrolyte. There the toner gets just eaten away i a short time, while after etching in ferric I have to remove it with acetone because it sticks still very good.


--- In Homebrew_PCBs@yahoogroups.com, Malcolm Parker-Lisberg <mparkerlisberg@...> wrote:
>
> Did you freeze the paper after thermal transfer, or just soak in water.
> Freezing for 20 mins. to 1/2 hour gives a denser transfer and easier paper removal.
>
> Malcolm
>
> I don't suffer from insanity I enjoy it!
> Mene, mene, tekel, upharsin
> The writing is on the wall.
> Ha-ktovet al ha-kir
>
> --------------------------------------------
> On Sun, 9/22/13, rolynd33 <roland.rasch@...> wrote:
>
> Subject: [Homebrew_PCBs] Some etched Artwork finished and questions on electrolytic etching
> To: Homebrew_PCBs@yahoogroups.com
> Date: Sunday, September 22, 2013, 11:18 AM
>
>
>
>
>
>
>
>
>
>
>
>
>
>
>
>
> Â
>
>
>
>
>
>
>
>
>
> I recently finished some etched Pendants.
>
> You can see sone photos here:
>
> http://brassgoggles.co.uk/forum/index.php/topic,41175.0.html
>
>
>
> I used the toner Transfer method and ferric chloride with
> good results . The etch is fairly deep compared to the usual
> etch depth needed for PCB but detail is still very good.
>
>
>
> I alternatively tried the electrolytic etch method with not
> so much sucess. I use canon Toner and it seems it does not
> hold up to a copper sulfate electrolyte. Its fine in
> chlorides though but the saltwater etch presented its own
> problems, a white precipitate forms on the etched piece
> eating the toner. Another member suggested HP toner.
>
> I want to try making the electrolytic etch to work, before I
> get myself a new/used HP printer I wanted to ask here if
> someone can confirm the usability of HP toner or maybe has
> experience with the electrolytic etch method and copper
> sulfate?
>

Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-22 by AlienRelics

Beautiful work! As others pointed out, the "failures" can be viewed as pre-aged successes.

Have you checked the database here? There is an editable database there of printers and toners that people have tried with toner transfer, with results. Also one for papers.

Please add your own experiences. When adding a printer/toner, be sure to specify which paper you are using, and vice versa.

Steve Greenfield AE7HD



--- In Homebrew_PCBs@yahoogroups.com, "rolynd33" <roland.rasch@...> wrote:
>
> I recently finished some etched Pendants.
> You can see sone photos here:
> http://brassgoggles.co.uk/forum/index.php/topic,41175.0.html
>
> I used the toner Transfer method and ferric chloride with good results . The etch is fairly deep compared to the usual etch depth needed for PCB but detail is still very good.
>
> I alternatively tried the electrolytic etch method with not so much sucess. I use canon Toner and it seems it does not hold up to a copper sulfate electrolyte. Its fine in chlorides though but the saltwater etch presented its own problems, a white precipitate forms on the etched piece eating the toner. Another member suggested HP toner.
> I want to try making the electrolytic etch to work, before I get myself a new/used HP printer I wanted to ask here if someone can confirm the usability of HP toner or maybe has experience with the electrolytic etch method and copper sulfate?
>

RE: Some etched Artwork finished and questions on electrolytic etching

2013-09-22 by <andrewm1973@...>

Rolynd,


Have you considered a spray etcher? Instead of being 1hr with ferric it would be more like 10mins for that depth shown in the photo.


I know it's not an answer to the electro etch question. If you are going to get into a lot of etching then the time saved is worth the effort building.



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

I recently finished some etched Pendants.
You can see sone photos here:
http://brassgoggles.co.uk/forum/index.php/topic,41175.0.html

I used the toner Transfer method and ferric chloride with good results . The etch is fairly deep compared to the usual etch depth needed for PCB but detail is still very good.

I alternatively tried the electrolytic etch method with not so much sucess. I use canon Toner and it seems it does not hold up to a copper sulfate electrolyte. Its fine in chlorides though but the saltwater etch presented its own problems, a white precipitate forms on the etched piece eating the toner. Another member suggested HP toner.
I want to try making the electrolytic etch to work, before I get myself a new/used HP printer I wanted to ask here if someone can confirm the usability of HP toner or maybe has experience with the electrolytic etch method and copper sulfate?

Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-23 by rolynd33

I have considerer the use of a spray etcher, would be nice to be able to make some double sided etching/cutouts but thats still on the design board.
Problem for a "real" spray etcher is finding the right pumps over here without having to spend a fortune.
There are the rotary tube thingies but thats more of a splash etcher than spray.

I searched the group for electroetching but ther is not much to find other than another guy having the same problems.
electroetch would be far easier to set up for double sided etching if I could get this to work.

Since here is THE place for toner transfer I thought to ask my questions here first.

RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-23 by <andrewm1973@...>

<quote>finding the right pumps over here without having to spend a fortune</quote>


Where is "Over here"


<quote>There are the rotary tube thingies but thats more of a splash etcher than spray</quote>


Sorry. Don't understand. There is some pretty vigorous "spray" happening here


http://www.instructables.com/id/The-Etchinator-low-cost-spray-etcher/


(go to step 17)



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

I have considerer the use of a spray etcher, would be nice to be able to make some double sided etching/cutouts but thats still on the design board.
Problem for a "real" spray etcher is finding the right pumps over here without having to spend a fortune.
There are the rotary tube thingies but thats more of a splash etcher than spray.

I searched the group for electroetching but ther is not much to find other than another guy having the same problems.
electroetch would be far easier to set up for double sided etching if I could get this to work.

Since here is THE place for toner transfer I thought to ask my questions here first.

Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-23 by rolynd33

"over here" is germany...sry. There are some commercial suppliers for acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make some "spray" of sorts but the droplets are much larger than the spray with nozzles and pump. Both methods work, but all the professional Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is not overly much to find in terms of user feedback but one of the problems reported was banding in some areas while etching and that the lower parts are always slightly overetched due to the etchant running off downwards when the plates are vertical.

This would also be a concern with the nozzle type, some means of constantly moving either nozzles or the workpiece would be needed to etch a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to produce less undercut than traditional method is cheaper in the long run and it would be much easier to use a setup with two electrodes(Kathode) and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate electolyte, it gets gradually eaten away before the etch is finished. If I can find a toner that will work its by far the easier method.

RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-23 by <andrewm1973@...>

Spray etchers (using diaphram pumps) I have seen have droplets not mist.


The point of the droplets is to have some weight behind the impact to move the insoluble precipitate. I would imagine an atomized mist be very ineffective with FeCl3.


If you look on ebay at the ceramic nozzles for sale for spray etchers, they are definitly not atomizing nozzles. They are a fan pattern


The banding I had with the spray etcher was only in early builds before I found the solution to stop it.


As far as etching the bottom of the plate more. With the spray-tube etcher you can actually etch the top of the plate more depending on motor speed. At lower speeds the bottom etches more. At higher speeds the top etches more. Find the "Sweet spot" for your tube and it is pretty even. Better than most nozzle/pump spray etchers I have seen that don't hold the target horizontal.


If you want to build a pump/nozzle spray etcher that does a better job than the rotary tube types you are GOING to have to move the nozzles or the target. As stated above the proper nozzles are a fan pattern. Large professional ones move the target through the machine. Smaller ones (Adam Seychell) move the nozzles back and forth.


WRT the toner not holding up in electro etch. Have you thought about dropping toner transfer and moving to photo-resist. It's a lot more convenient if you are producing the same design over and over again. It also does MUCH better results on long etches (thick brass)



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

"over here" is germany...sry. There are some commercial suppliers for acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make some "spray" of sorts but the droplets are much larger than the spray with nozzles and pump. Both methods work, but all the professional Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is not overly much to find in terms of user feedback but one of the problems reported was banding in some areas while etching and that the lower parts are always slightly overetched due to the etchant running off downwards when the plates are vertical.

This would also be a concern with the nozzle type, some means of constantly moving either nozzles or the workpiece would be needed to etch a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to produce less undercut than traditional method is cheaper in the long run and it would be much easier to use a setup with two electrodes(Kathode) and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate electolyte, it gets gradually eaten away before the etch is finished. If I can find a toner that will work its by far the easier method.

RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-23 by <roland.rasch@...>

Thanks very much for the Info! A rotary type would also be cheaper to realize, so If I get to build one then I will probably go for a rotary tube one.


Toner transfer is easy to do and cheap, so far I am satisfied with my results I dont have a very high faliure rate.


Photoresist would be another thing to have a look at. PCBs you can get precoated but brass copper and german silver sheet does not come precoated. But there are some Photoresist films out there like pureetch , z-acryl, Image-on and the like. These would surely be easier to apply than coating with laquer. I will have to do some research on these. AFAIK real photo negatives work best as a mask for exposing, I have read in passing ,but with no real focus on this kind of topic, that there could be some problems with laser printed masks not dense enough, but surely this could also be solved.


While reading on some older patents on etching machines I stumbled on something only briefly mentioned, apparently they used a small amount of oil in the etchant (how much and what kind etc was not specified(just : "as known to those familiar with the craft" etc etc.) to lessen the undercut. The oil would cling more firmly to the walls of th etched grooves slowing the etching there while being washed away on the bottom of the grooves by the action of the spray. Ever heard of this?




--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Spray etchers (using diaphram pumps) I have seen have droplets not mist.


The point of the droplets is to have some weight behind the impact to move the insoluble precipitate. I would imagine an atomized mist be very ineffective with FeCl3.


If you look on ebay at the ceramic nozzles for sale for spray etchers, they are definitly not atomizing nozzles. They are a fan pattern


The banding I had with the spray etcher was only in early builds before I found the solution to stop it.


As far as etching the bottom of the plate more. With the spray-tube etcher you can actually etch the top of the plate more depending on motor speed. At lower speeds the bottom etches more. At higher speeds the top etches more. Find the "Sweet spot" for your tube and it is pretty even. Better than most nozzle/pump spray etchers I have seen that don't hold the target horizontal.


If you want to build a pump/nozzle spray etcher that does a better job than the rotary tube types you are GOING to have to move the nozzles or the target. As stated above the proper nozzles are a fan pattern. Large professional ones move the target through the machine. Smaller ones (Adam Seychell) move the nozzles back and forth.


WRT the toner not holding up in electro etch. Have you thought about dropping toner transfer and moving to photo-resist. It's a lot more convenient if you are producing the same design over and over again. It also does MUCH better results on long etches (thick brass)



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

"over here" is germany...sry. There are some commercial suppliers for acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make some "spray" of sorts but the droplets are much larger than the spray with nozzles and pump. Both methods work, but all the professional Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is not overly much to find in terms of user feedback but one of the problems reported was banding in some areas while etching and that the lower parts are always slightly overetched due to the etchant running off downwards when the plates are vertical.

This would also be a concern with the nozzle type, some means of constantly moving either nozzles or the workpiece would be needed to etch a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to produce less undercut than traditional method is cheaper in the long run and it would be much easier to use a setup with two electrodes(Kathode) and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate electolyte, it gets gradually eaten away before the etch is finished. If I can find a toner that will work its by far the easier method.

RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-25 by <andrewm1973@...>

Rotary one for an area 1/4 of an A4 sheet of paper should be able to be cobbled together for much less than $100. If you want to go for something more like a full sheet of A4 paper then pump is a better option. Here in Aus the right pumps are $150..$200


I coat my own brass with dry film photo resist. Look at Adam Seychells PDF on how to do this. It is same ball park price to do it with photo as it is to use Pulsar paper PLUS the TRF film. It's just a bit dearer to set up equipment at the start. The quality and repeatability is miles ahead. You never ever get pinholes / pitting with photoresist.


Inkjet printers onto ink-jet transperancies purchased from screen printing places work great. Much better than laser in my experience unless you have a small car sized/price laser printer.


The dry film resist has fairly good contrast, but a good photo tool never goes astray. Small home office lasers (Like my HP4xxx) don't do good solid blacks on large areas. Toner enhancement spray helps a bit but (some) inkjets just work better for this and are much cheaper.


I have no knowledge of oil to prevent undercut. It sounds interesting though as I often etch 0.7mm brass.



---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Thanks very much for the Info! A rotary type would also be cheaper to realize, so If I get to build one then I will probably go for a rotary tube one.


Toner transfer is easy to do and cheap, so far I am satisfied with my results I dont have a very high faliure rate.


Photoresist would be another thing to have a look at. PCBs you can get precoated but brass copper and german silver sheet does not come precoated. But there are some Photoresist films out there like pureetch , z-acryl, Image-on and the like. These would surely be easier to apply than coating with laquer. I will have to do some research on these. AFAIK real photo negatives work best as a mask for exposing, I have read in passing ,but with no real focus on this kind of topic, that there could be some problems with laser printed masks not dense enough, but surely this could also be solved.


While reading on some older patents on etching machines I stumbled on something only briefly mentioned, apparently they used a small amount of oil in the etchant (how much and what kind etc was not specified(just : "as known to those familiar with the craft" etc etc.) to lessen the undercut. The oil would cling more firmly to the walls of th etched grooves slowing the etching there while being washed away on the bottom of the grooves by the action of the spray. Ever heard of this?




--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Spray etchers (using diaphram pumps) I have seen have droplets not mist.


The point of the droplets is to have some weight behind the impact to move the insoluble precipitate. I would imagine an atomized mist be very ineffective with FeCl3.


If you look on ebay at the ceramic nozzles for sale for spray etchers, they are definitly not atomizing nozzles. They are a fan pattern


The banding I had with the spray etcher was only in early builds before I found the solution to stop it.


As far as etching the bottom of the plate more. With the spray-tube etcher you can actually etch the top of the plate more depending on motor speed. At lower speeds the bottom etches more. At higher speeds the top etches more. Find the "Sweet spot" for your tube and it is pretty even. Better than most nozzle/pump spray etchers I have seen that don't hold the target horizontal.


If you want to build a pump/nozzle spray etcher that does a better job than the rotary tube types you are GOING to have to move the nozzles or the target. As stated above the proper nozzles are a fan pattern. Large professional ones move the target through the machine. Smaller ones (Adam Seychell) move the nozzles back and forth.


WRT the toner not holding up in electro etch. Have you thought about dropping toner transfer and moving to photo-resist. It's a lot more convenient if you are producing the same design over and over again. It also does MUCH better results on long etches (thick brass)



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

"over here" is germany...sry. There are some commercial suppliers for acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make some "spray" of sorts but the droplets are much larger than the spray with nozzles and pump. Both methods work, but all the professional Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is not overly much to find in terms of user feedback but one of the problems reported was banding in some areas while etching and that the lower parts are always slightly overetched due to the etchant running off downwards when the plates are vertical.

This would also be a concern with the nozzle type, some means of constantly moving either nozzles or the workpiece would be needed to etch a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to produce less undercut than traditional method is cheaper in the long run and it would be much easier to use a setup with two electrodes(Kathode) and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate electolyte, it gets gradually eaten away before the etch is finished. If I can find a toner that will work its by far the easier method.

RE: [Homebrew_PCBs] RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-25 by Andrew Volk

Andrew-

I’m not in Australia (in US), but what kind of pumps are you talking about for pumping etchants?

From: Homebrew_PCBs@yahoogroups.com [mailto:Homebrew_PCBs@yahoogroups.com] On Behalf Of andrewm1973@...
Sent: Tuesday, September 24, 2013 5:37 PM
To: Homebrew_PCBs@yahoogroups.com
Subject: [Homebrew_PCBs] RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

Rotary one for an area 1/4 of an A4 sheet of paper should be able to be cobbled together for much less than $100. If you want to go for something more like a full sheet of A4 paper then pump is a better option. Here in Aus the right pumps are $150..$200

I coat my own brass with dry film photo resist. Look at Adam Seychells PDF on how to do this. It is same ball park price to do it with photo as it is to use Pulsar paper PLUS the TRF film. It's just a bit dearer to set up equipment at the start. The quality and repeatability is miles ahead. You never ever get pinholes / pitting with photoresist.

Inkjet printers onto ink-! jet transperancies purchased from screen printing places work great. Much better than laser in my experience unless you have a small car sized/price laser printer.

The dry film resist has fairly good contrast, but a good photo tool never goes astray. Small home office lasers (Like my HP4xxx) don't do good solid blacks on large areas. Toner enhancement spray helps a bit but (some) inkjets just work better for this and are much cheaper.

I have no knowledge of oil to prevent undercut. It sounds interesting though as I often etch 0.7mm brass.



---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Thanks very much for the Info! A rotary type would also be cheaper to realize, so If I get to build one then I will probably go for a rotary tube one.

Toner transfer is easy to do and cheap, so far I am satisfied with my results I dont have a very high faliure rate.

Photoresist would be another thing to have a look at. PCBs you can get precoated but brass copper and german silver sheet does not come precoated. But there are some Photoresist films out there like pureetch , z-acryl, Image-on and the like. These would surely be easier to appl! y than coating with laquer. I will have to do some research on these. AFAIK real photo negatives work best as a mask for exposing, I have read in passing ,but with no real focus on this kind of topic, that there could be some problems with laser printed masks not dense enough, but surely this could also be solved.

While reading on some older patents on etching machines I stumbled on something only briefly mentioned, apparently they used a small amount of oil in the etchant (how much and what kind etc was not specified(just : "as known to those familiar with the craft" etc etc.) to lessen the undercut. The oil would cling more firmly to the walls of th etched grooves slowing the etching there while being washed away on the bottom of the grooves by the action of the s! pray. Ever heard of this?

--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Spray etchers (using diaphram pumps) I have seen have droplets not mist.

The point of the droplets is to have some weight behind the impact to move the insoluble precipitate. I would imagine an atomized mist be very ineffective with FeCl3.

If you look on ebay at the ceramic nozzles for sale for spray! etchers, they are definitly not atomizing nozzles. They are a fan pattern

The banding I had with the spray etcher was only in early builds before I found the solution to stop it.

As far as etching the bottom of the plate more. With the spray-tube etcher you can actually etch the top of the plate more depending on motor speed. At lower speeds the bottom etches more. At higher speeds the top etches more. Find the "Sweet spot" for your tube and it is pretty even. Better than most nozzle/pump spray etchers I have seen that don't hold th! e target horizontal.

If you want to build a pump/nozzle spray etcher that does a better job than the rotary tube types you are GOING to have to move the nozzles or the target. As stated above the proper nozzles are a fan pattern. Large professional ones move the target through the machine. Smaller ones (Adam Seychell) move the nozzles back and forth.

WRT the toner not holding up in electro etch. Have you thought about dropping toner transfer and moving to photo-resist. It's a lot more convenient if you are producing the same design over and over again. &n! bsp;It also does MUCH better results on long etches (thick brass)

--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

"over here" is germany...sry. There are some commercial suppliers for acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make some "spray" of sorts but the droplets are much larger than the spray with nozzles and pump. Both methods work, but all the professional Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is not overly much to find in terms of user feedback but one of the problems reported was banding in some areas while etching and that the lower parts are always slightly overetched due to the etchant running off downwards when the plates are vertical.

This would also be a concern with the nozzle type, some means of constantly moving either nozzles or the workpiece would be needed to etch a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to produce less undercut than traditional method is cheaper in the long run and it would be much easier to use a setup with two electrodes(Kathode) and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate electolyte, it gets gradually eaten away before the etch is finished. If I can find a toner that will work its by far the easier method.

RE: RE: [Homebrew_PCBs] RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-25 by <andrewm1973@...>


A flojet not a shureflow according to Mr Seychell


http://groups.yahoo.com/neo/groups/Homebrew_PCBs/conversations/topics/8414




---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Andrew-

I’m not in Australia (in US), but what kind of pumps are you talking about for pumping etchants?

From: Homebrew_PCBs@yahoogroups.com [mailto:Homebrew_PCBs@yahoogroups.com] On Behalf Of andrewm1973@...
Sent: Tuesday, September 24, 2013 5:37 PM
To: Homebrew_PCBs@yahoogroups.com
Subject: [Homebrew_PCBs] RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

Rotary one for an area 1/4 of an A4 sheet of paper should be able to be cobbled together for much less than $100. If you want to go for something more like a full sheet of A4 paper then pump is a better option. Here in Aus the right pumps are $150..$200

I coat my own brass with dry film photo resist. Look at Adam Seychells PDF on how to do this. It is same ball park price to do it with photo as it is to use Pulsar paper PLUS the TRF film. It's just a bit dearer to set up equipment at the start. The quality and repeatability is miles ahead. You never ever get pinholes / pitting with photoresist.

Inkjet printers onto ink-! jet transperancies purchased from screen printing places work great. Much better than laser in my experience unless you have a small car sized/price laser printer.

The dry film resist has fairly good contrast, but a good photo tool never goes astray. Small home office lasers (Like my HP4xxx) don't do good solid blacks on large areas. Toner enhancement spray helps a bit but (some) inkjets just work better for this and are much cheaper.

I have no knowledge of oil to prevent undercut. It sounds interesting though as I often etch 0.7mm brass.



---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Thanks very much for the Info! A rotary type would also be cheaper to realize, so If I get to build one then I will probably go for a rotary tube one.

Toner transfer is easy to do and cheap, so far I am satisfied with my results I dont have a very high faliure rate.

Photoresist would be another thing to have a look at. PCBs you can get precoated but brass copper and german silver sheet does not come precoated. But there are some Photoresist films out there like pureetch , z-acryl, Image-on and the like. These would surely be easier to appl! y than coating with laquer. I will have to do some research on these. AFAIK real photo negatives work best as a mask for exposing, I have read in passing ,but with no real focus on this kind of topic, that there could be some problems with laser printed masks not dense enough, but surely this could also be solved.

While reading on some older patents on etching machines I stumbled on something only briefly mentioned, apparently they used a small amount of oil in the etchant (how much and what kind etc was not specified(just : "as known to those familiar with the craft" etc etc.) to lessen the undercut. The oil would cling more firmly to the walls of th etched grooves slowing the etching there while being washed away on the bottom of the grooves by the action of the s! pray. Ever heard of this?

--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Spray etchers (using diaphram pumps) I have seen have droplets not mist.

The point of the droplets is to have some weight behind the impact to move the insoluble precipitate. I would imagine an atomized mist be very ineffective with FeCl3.

If you look on ebay at the ceramic nozzles for sale for spray! etchers, they are definitly not atomizing nozzles. They are a fan pattern

The banding I had with the spray etcher was only in early builds before I found the solution to stop it.

As far as etching the bottom of the plate more. With the spray-tube etcher you can actually etch the top of the plate more depending on motor speed. At lower speeds the bottom etches more. At higher speeds the top etches more. Find the "Sweet spot" for your tube and it is pretty even. Better than most nozzle/pump spray etchers I have seen that don't hold th! e target horizontal.

If you want to build a pump/nozzle spray etcher that does a better job than the rotary tube types you are GOING to have to move the nozzles or the target. As stated above the proper nozzles are a fan pattern. Large professional ones move the target through the machine. Smaller ones (Adam Seychell) move the nozzles back and forth.

WRT the toner not holding up in electro etch. Have you thought about dropping toner transfer and moving to photo-resist. It's a lot more convenient if you are producing the same design over and over again. &n! bsp;It also does MUCH better results on long etches (thick brass)

--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

"over here" is germany...sry. There are some commercial suppliers for acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make some "spray" of sorts but the droplets are much larger than the spray with nozzles and pump. Both methods work, but all the professional Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is not overly much to find in terms of user feedback but one of the problems reported was banding in some areas while etching and that the lower parts are always slightly overetched due to the etchant running off downwards when the plates are vertical.

This would also be a concern with the nozzle type, some means of constantly moving either nozzles or the workpiece would be needed to etch a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to produce less undercut than traditional method is cheaper in the long run and it would be much easier to use a setup with two electrodes(Kathode) and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate electolyte, it gets gradually eaten away before the etch is finished. If I can find a toner that will work its by far the easier method.

Re: [Homebrew_PCBs] RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-25 by <n0tt1@...>

Just for discussion here....
I gotta ask about using "oil" (or whatever) with etchant. Let's
say that it DOES prevent undercut...what would be the chemical
process going on if it prevents undercut and yet does
a good job of removing the unwanted /unprotected copper?
Maybe the "oil"-etchant just works faster so that it doesn't
have TIME to do any significant undercutting?

Charlie

On 24 Sep 2013 17:36:35 -0700 <andrewm1973@...> writes:

Rotary one for an area 1/4 of an A4 sheet of paper should be able to be
cobbled together for much less than $100. If you want to go for
something more like a full sheet of A4 paper then pump is a better
option. Here in Aus the right pumps are $150..$200


I coat my own brass with dry film photo resist. Look at Adam Seychells
PDF on how to do this. It is same ball park price to do it with photo as
it is to use Pulsar paper PLUS the TRF film. It's just a bit dearer to
set up equipment at the start. The quality and repeatability is miles
ahead. You never ever get pinholes / pitting with photoresist.


Inkjet printers onto ink-jet transperancies purchased from screen
printing places work great. Much better than laser in my experience
unless you have a small car sized/price laser printer.


The dry film resist has fairly good contrast, but a good photo tool never
goes astray. Small home office lasers (Like my HP4xxx) don't do good
solid blacks on large areas. Toner enhancement spray helps a bit but
(some) inkjets just work better for this and are much cheaper.


I have no knowledge of oil to prevent undercut. It sounds interesting
though as I often etch 0.7mm brass.


---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com>
wrote:


Thanks very much for the Info! A rotary type would also be cheaper to
realize, so If I get to build one then I will probably go for a rotary
tube one.


Toner transfer is easy to do and cheap, so far I am satisfied with my
results I dont have a very high faliure rate.


Photoresist would be another thing to have a look at. PCBs you can get
precoated but brass copper and german silver sheet does not come
precoated. But there are some Photoresist films out there like pureetch ,
z-acryl, Image-on and the like. These would surely be easier to apply
than coating with laquer. I will have to do some research on these.
AFAIK real photo negatives work best as a mask for exposing, I have read
in passing ,but with no real focus on this kind of topic, that there
could be some problems with laser printed masks not dense enough, but
surely this could also be solved.


While reading on some older patents on etching machines I stumbled on
something only briefly mentioned, apparently they used a small amount of
oil in the etchant (how much and what kind etc was not specified(just :
"as known to those familiar with the craft" etc etc.) to lessen the
undercut. The oil would cling more firmly to the walls of th etched
grooves slowing the etching there while being washed away on the bottom
of the grooves by the action of the spray. Ever heard of this?






--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com>
wrote:


Spray etchers (using diaphram pumps) I have seen have droplets not mist.


The point of the droplets is to have some weight behind the impact to
move the insoluble precipitate. I would imagine an atomized mist be very
ineffective with FeCl3.


If you look on ebay at the ceramic nozzles for sale for spray etchers,
they are definitly not atomizing nozzles. They are a fan pattern


The banding I had with the spray etcher was only in early builds before I
found the solution to stop it.


As far as etching the bottom of the plate more. With the spray-tube
etcher you can actually etch the top of the plate more depending on motor
speed. At lower speeds the bottom etches more. At higher speeds the top
etches more. Find the "Sweet spot" for your tube and it is pretty even.
Better than most nozzle/pump spray etchers I have seen that don't hold
the target horizontal.


If you want to build a pump/nozzle spray etcher that does a better job
than the rotary tube types you are GOING to have to move the nozzles or
the target. As stated above the proper nozzles are a fan pattern. Large
professional ones move the target through the machine. Smaller ones
(Adam Seychell) move the nozzles back and forth.


WRT the toner not holding up in electro etch. Have you thought about
dropping toner transfer and moving to photo-resist. It's a lot more
convenient if you are producing the same design over and over again. It
also does MUCH better results on long etches (thick brass)



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com>
wrote:


"over here" is germany...sry. There are some commercial suppliers for
acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make
some "spray" of sorts but the droplets are much larger than the spray
with nozzles and pump. Both methods work, but all the professional
Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is
not overly much to find in terms of user feedback but one of the problems
reported was banding in some areas while etching and that the lower parts
are always slightly overetched due to the etchant running off downwards
when the plates are vertical.

This would also be a concern with the nozzle type, some means of
constantly moving either nozzles or the workpiece would be needed to etch
a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head
but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to
produce less undercut than traditional method is cheaper in the long run
and it would be much easier to use a setup with two electrodes(Kathode)
and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate
electolyte, it gets gradually eaten away before the etch is finished. If
I can find a toner that will work its by far the easier method.


[Non-text portions of this message have been removed]

RE: Re: [Homebrew_PCBs] RE: RE: RE: Re: Some etched Artwork finished and questions on electrolytic etching

2013-09-25 by <roland.rasch@...>

These are called "shoulder protection" or "sidewall protection" chemical additives an are still in use but the composition is usually proprietary.


Found a little here:


http://www.freepatentsonline.com/3287191.html


this older one speaks of a mixture with oil:


http://www.freepatentsonline.com/3136323.html


Unfortunately most of the used chemicals are not easily to be had by the public.


Dont know how the purely chemical ones work,, the oil works by clinging to the etched plate and being washed away by the mechanical action of the spray but clinging better to the walls(shoulder) of the etched grooves lessening the etching action there and thus preventing or slowing down the undercut.



---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com> wrote:

Just for discussion here....
I gotta ask about using "oil" (or whatever) with etchant. Let's
say that it DOES prevent undercut...what would be the chemical
process going on if it prevents undercut and yet does
a good job of removing the unwanted /unprotected copper?
Maybe the "oil"-etchant just works faster so that it doesn't
have TIME to do any significant undercutting?

Charlie

On 24 Sep 2013 17:36:35 -0700 <andrewm1973@...> writes:

Rotary one for an area 1/4 of an A4 sheet of paper should be able to be
cobbled together for much less than $100. If you want to go for
something more like a full sheet of A4 paper then pump is a better
option. Here in Aus the right pumps are $150..$200


I coat my own brass with dry film photo resist. Look at Adam Seychells
PDF on how to do this. It is same ball park price to do it with photo as
it is to use Pulsar paper PLUS the TRF film. It's just a bit dearer to
set up equipment at the start. The quality and repeatability is miles
ahead. You never ever get pinholes / pitting with photoresist.


Inkjet printers onto ink-jet transperancies purchased from screen
printing places work great. Much better than laser in my experience
unless you have a small car sized/price laser printer.


The dry film resist has fairly good contrast, but a good photo tool never
goes astray. Small home office lasers (Like my HP4xxx) don't do good
solid blacks on large areas. Toner enhancement spray helps a bit but
(some) inkjets just work better for this and are much cheaper.


I have no knowledge of oil to prevent undercut. It sounds interesting
though as I often etch 0.7mm brass.


---In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com>
wrote:


Thanks very much for the Info! A rotary type would also be cheaper to
realize, so If I get to build one then I will probably go for a rotary
tube one.


Toner transfer is easy to do and cheap, so far I am satisfied with my
results I dont have a very high faliure rate.


Photoresist would be another thing to have a look at. PCBs you can get
precoated but brass copper and german silver sheet does not come
precoated. But there are some Photoresist films out there like pureetch ,
z-acryl, Image-on and the like. These would surely be easier to apply
than coating with laquer. I will have to do some research on these.
AFAIK real photo negatives work best as a mask for exposing, I have read
in passing ,but with no real focus on this kind of topic, that there
could be some problems with laser printed masks not dense enough, but
surely this could also be solved.


While reading on some older patents on etching machines I stumbled on
something only briefly mentioned, apparently they used a small amount of
oil in the etchant (how much and what kind etc was not specified(just :
"as known to those familiar with the craft" etc etc.) to lessen the
undercut. The oil would cling more firmly to the walls of th etched
grooves slowing the etching there while being washed away on the bottom
of the grooves by the action of the spray. Ever heard of this?






--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com>
wrote:


Spray etchers (using diaphram pumps) I have seen have droplets not mist.


The point of the droplets is to have some weight behind the impact to
move the insoluble precipitate. I would imagine an atomized mist be very
ineffective with FeCl3.


If you look on ebay at the ceramic nozzles for sale for spray etchers,
they are definitly not atomizing nozzles. They are a fan pattern


The banding I had with the spray etcher was only in early builds before I
found the solution to stop it.


As far as etching the bottom of the plate more. With the spray-tube
etcher you can actually etch the top of the plate more depending on motor
speed. At lower speeds the bottom etches more. At higher speeds the top
etches more. Find the "Sweet spot" for your tube and it is pretty even.
Better than most nozzle/pump spray etchers I have seen that don't hold
the target horizontal.


If you want to build a pump/nozzle spray etcher that does a better job
than the rotary tube types you are GOING to have to move the nozzles or
the target. As stated above the proper nozzles are a fan pattern. Large
professional ones move the target through the machine. Smaller ones
(Adam Seychell) move the nozzles back and forth.


WRT the toner not holding up in electro etch. Have you thought about
dropping toner transfer and moving to photo-resist. It's a lot more
convenient if you are producing the same design over and over again. It
also does MUCH better results on long etches (thick brass)



--- In Homebrew_PCBs@yahoogroups.com, <homebrew_pcbs@yahoogroups.com>
wrote:


"over here" is germany...sry. There are some commercial suppliers for
acid resistant pumps but they are not cheap, quite the opposite.

By spray I mean finely atomized with nozzles, the "etchinator" does make
some "spray" of sorts but the droplets are much larger than the spray
with nozzles and pump. Both methods work, but all the professional
Etching is done with the spray nozzle type.
I have heard some good and some bad from the rotary tube type, there is
not overly much to find in terms of user feedback but one of the problems
reported was banding in some areas while etching and that the lower parts
are always slightly overetched due to the etchant running off downwards
when the plates are vertical.

This would also be a concern with the nozzle type, some means of
constantly moving either nozzles or the workpiece would be needed to etch
a larger plate (A5-a4 size) in an even way.

So far a etching machine of either type is still in the back of my head
but I was not willing to go thruh the trouble of building one.

I would rather try and make the electroetch work since it seems to
produce less undercut than traditional method is cheaper in the long run
and it would be much easier to use a setup with two electrodes(Kathode)
and the workpiece(anode) in the middle to make some double sided etching.
I am not sucessful because my toner does not hold up in copper sulfate
electolyte, it gets gradually eaten away before the etch is finished. If
I can find a toner that will work its by far the easier method.


[Non-text portions of this message have been removed]