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Pb-free reflow scorches PCBs with no soldermask

Pb-free reflow scorches PCBs with no soldermask

2011-03-09 by John Wilson

Hello there! This is probably a dumb question but I can't find anything in
the list archives (but then again maybe I'm searching for the wrong word).

I'm trying to get the hang of reflow soldering of small 2-layer PCBs with
no solder mask, at Pb-free temps using a toaster oven. The problem I'm
having is that I can't get the solder to melt w/o scorching the boards.
I assume that means I'm being an idiot in some way, but come to think of
it, all of the examples I've found on the web showing how great toaster
oven reflow is seem to show boards *with* soldermask (which might protect
the board from heat somewhat and/or make the scorching hard to see) and/or
using Sn/Pb paste (which melts at a lower temp). So maybe what I'm trying
to do is unrealistic? I've done a whole series of the boards at different
max temps and the progression is obvious:

Looks perfect = doesn't work.
Very faint suntan = doesn't work.
A bit scorched = works fine.
Cajun style (burned to a crisp) = works fine!

So basically my question is: has anyone had good luck reflowing boards
at lead-free temperatures w/o soldermask? If so, was there anything tricky
about it?

I've had decent success soldering these boards with a hot air pencil (set to
325 C but I don't believe it) and a preheater. The only problem is shorts
underneath one of the components, so a lot of boards fail when I test them,
and I figure real reflowing is the answer. I sell these boards so they
have to be Pb-free, and I stuff them by hand so I've never bothered with
solder mask (just being careful has been good enough -- until this new rev
with the SMT 7-seg LED that gets the shorts).

Details in case they matter:
- PCBs = from Advanced Circuits (regular FR4 laminate IIRC)
- paste = Ameritronics ZeroLead (96.5 Sn / 3 Ag / 0.5 Cu -- MP = 217-219 C)
- soak = 150 C to 217 C (max rate = 0.6 C per second)
- reflow temp = 230 C max (max rate = 1.6 C per second)
- oven = Black & Decker Infrawave driven by Arduino with SparkFun thermocouple
and MAX6675 chip and my own software -- yes I know that sounds fishy but
my cheapskate Harbor Freight IR thermometer agrees with the measured temps
and so (eventually) does a regular oven thermometer, so I'm fairly sure
the temps are accurate enough

There's an article in QST (ham magazine) by someone who got excellent results
just running the toaster by hand (with a thermocouple-equipped multimeter).
So how stupid do I have to be to ruin piles of PCBs (and stink up my house)
with precise computer control? Lay it on me!

Thanks,

John Wilson
D Bit

Re: [Homebrew_PCBs] Pb-free reflow scorches PCBs with no soldermask

2011-03-09 by Adam Shea

Does it work any better if you hold at 175C for 5 minutes or so? The
times I've had trouble with lead-free reflow is when I don't get the
board up to temp on the soak. Most parts (Si especially) should be fine
with a few minutes unpowered at 175C. (Most newer IGBTs even work at
250C though the packaging doesn't like it much).

--Adam Shea.

Show quoted textHide quoted text
On 03/09/11 02:33, John Wilson wrote:
> Hello there! This is probably a dumb question but I can't find anything in
> the list archives (but then again maybe I'm searching for the wrong word).
>
> I'm trying to get the hang of reflow soldering of small 2-layer PCBs with
> no solder mask, at Pb-free temps using a toaster oven. The problem I'm
> having is that I can't get the solder to melt w/o scorching the boards.
> I assume that means I'm being an idiot in some way, but come to think of
> it, all of the examples I've found on the web showing how great toaster
> oven reflow is seem to show boards *with* soldermask (which might protect
> the board from heat somewhat and/or make the scorching hard to see) and/or
> using Sn/Pb paste (which melts at a lower temp). So maybe what I'm trying
> to do is unrealistic? I've done a whole series of the boards at different
> max temps and the progression is obvious:
>
> Looks perfect = doesn't work.
> Very faint suntan = doesn't work.
> A bit scorched = works fine.
> Cajun style (burned to a crisp) = works fine!
>
> So basically my question is: has anyone had good luck reflowing boards
> at lead-free temperatures w/o soldermask? If so, was there anything tricky
> about it?
>
> I've had decent success soldering these boards with a hot air pencil (set to
> 325 C but I don't believe it) and a preheater. The only problem is shorts
> underneath one of the components, so a lot of boards fail when I test them,
> and I figure real reflowing is the answer. I sell these boards so they
> have to be Pb-free, and I stuff them by hand so I've never bothered with
> solder mask (just being careful has been good enough -- until this new rev
> with the SMT 7-seg LED that gets the shorts).
>
> Details in case they matter:
> - PCBs = from Advanced Circuits (regular FR4 laminate IIRC)
> - paste = Ameritronics ZeroLead (96.5 Sn / 3 Ag / 0.5 Cu -- MP = 217-219 C)
> - soak = 150 C to 217 C (max rate = 0.6 C per second)
> - reflow temp = 230 C max (max rate = 1.6 C per second)
> - oven = Black & Decker Infrawave driven by Arduino with SparkFun thermocouple
> and MAX6675 chip and my own software -- yes I know that sounds fishy but
> my cheapskate Harbor Freight IR thermometer agrees with the measured temps
> and so (eventually) does a regular oven thermometer, so I'm fairly sure
> the temps are accurate enough
>
> There's an article in QST (ham magazine) by someone who got excellent results
> just running the toaster by hand (with a thermocouple-equipped multimeter).
> So how stupid do I have to be to ruin piles of PCBs (and stink up my house)
> with precise computer control? Lay it on me!
>
> Thanks,
>
> John Wilson
> D Bit
>
>
> ------------------------------------
>
> Be sure to visit the group home and check for new Links, Files, and Photos:
> http://groups.yahoo.com/group/Homebrew_PCBsYahoo! Groups Links
>
>
>




[Non-text portions of this message have been removed]

Re: Pb-free reflow scorches PCBs with no soldermask

2011-03-10 by kc1p

--- In Homebrew_PCBs@yahoogroups.com, Adam Shea <shea0097@...> wrote:
Show quoted textHide quoted text
> Does it work any better if you hold at 175C for 5 minutes or so? The
> times I've had trouble with lead-free reflow is when I don't get the
> board up to temp on the soak.

It was worth a shot, but no, it weathered the 5 minutes at 175 just
fine but then got cooked when it ramped up to 230 C. Thanks, though!

John Wilson
D Bit

Re: Pb-free reflow scorches PCBs with no soldermask

2011-03-10 by jmelson2

--- In Homebrew_PCBs@yahoogroups.com, John Wilson <wilson@...> wrote:
Show quoted textHide quoted text
>
> Hello there! This is probably a dumb question but I can't find anything in
> the list archives (but then again maybe I'm searching for the wrong word).
>
> I'm trying to get the hang of reflow soldering of small 2-layer PCBs with
> no solder mask, at Pb-free temps using a toaster oven. The problem I'm
> having is that I can't get the solder to melt w/o scorching the boards.
>
I tried to do this, and found that controlling temperature with a thermocouple in air severely overheated the boards. It has nothing to do with soldermask. The boards turned out black in spots and with delaminations.

The fix was to poke the thermocouple into a through hole near the middle of the board. This way, the temp controller is sensing the ACTUAL board temperature, which apparently is hotter than the surrounding air, due to the IR from the heating elements.

I use a ramp and soak thermocouple controller. I set it to heat at 2 degree C per minute to 180 C, hold there for one minute, then heat to 245 C at 3 C / min, hold at 245 for one minute, and then ramp down at 5 C/min, although the oven doesn't cool that quickly.

Also, of course, I use boards made of FR-406 for the lead-free, as they are made to stand the temperature. Plain FR4 cannot safely handle it. Some batches will take it with slight discoloration, some others will bubble and split.

And, of course, if you are not controlling temperature with a precision sensor inside the oven, all bets are off. The oven thermostat will cook a pizza, but is WAY too inaccurate for reflow soldering.

Jon

Re: Pb-free reflow scorches PCBs with no soldermask

2011-03-10 by kc1p

--- In Homebrew_PCBs@yahoogroups.com, "jmelson2" <elson@...> wrote:
>The fix was to poke the thermocouple into a through hole near
>the middle of the board. This way, the temp controller is sensing
>the ACTUAL board temperature, which apparently is hotter than the
>surrounding air, due to the IR from the heating elements.

Hey, I think you're on to something here! I'm running out of loaded
boards to test on but the one I tried your way came out great --
thanks!!!

I also tried a different empty board *with* soldermask (unknown
laminate -- it's just a cheapy Futurlec SMT/DIP adapter I wouldn't
mind frying) with the thermocouple in the air and it came out OK
too. Since I varied more than one parameter (soldermask and maybe
laminate), that doesn't prove anything, but it does make me wish I
hadn't ordered a near-lifetime supply of non-soldermask PCBs last
time around.

Show quoted textHide quoted text
>I use a ramp and soak thermocouple controller. [...]

Awesome -- thanks for the numbers. (I'll assume all those
degrees/min rates are actually degrees/sec.) They're similar to
mine, but different, so the difference may be critical.

Thank you!!

John Wilson
D Bit

Re: Pb-free reflow scorches PCBs with no soldermask

2011-03-11 by jmelson2

--- In Homebrew_PCBs@yahoogroups.com, "kc1p" <wilson@...> wrote:
Show quoted textHide quoted text
>
> --- In Homebrew_PCBs@yahoogroups.com, "jmelson2" <elson@> wrote:
> >The fix was to poke the thermocouple into a through hole near
> >the middle of the board. This way, the temp controller is sensing
> >the ACTUAL board temperature, which apparently is hotter than the
> >surrounding air, due to the IR from the heating elements.
>
> Hey, I think you're on to something here! I'm running out of loaded
> boards to test on but the one I tried your way came out great --
> thanks!!!
Well, I've been doing production boards in both lead-solder and lead-free for 4 years now with this setup, and it works quite reliably. It is a bit more of a bother to reach into the oven and poke the thermocouple into the hole without knocking any parts out of alignment, but the other way sure didn't work at all.

I did luck into a roll of micro thermocouple wire on eBay and a good deal on a ramp and soak controller that would cost $800+ new.

Jon