Did some experimenting... I have now etched away the copper of both welding rods, which nicely saturated my etchant too... 1 rod is 8mm * 22cm i think which is 55 square cm. i connected both rods together to get ~~100 square centimeters. for the other electrode i used a copper wire, diameter about 4mm and length 10cm. which is 12,5cm square. i can only prevent chlorine gas by currents well below 0,5A (you know it is hard to tell when there is really no gas). - that would be 5mA / square cm at the carbon then. However i think the area of the copper wire is too big, i can not get hydrogen at all, even if there is severe chlorine. so i assumed it is too big and now i use a 1.5mm^2 wire immersed only 2 centimeters. now i get hydrogen before i get chlorine. I have it running at 150mA right now, and will see if it works. The copper plates like a sponge, and it is kind of hard to get it out without shaking it all off again (and loosing it in the etchant). It is funny how the copper grows. I suspect the area hugely increases when the first copper is deposited and the current density is wrong again. I must say right now it is not looking very well. the etchant is much darker than it should be and all the experiments have not yet managed to regenerate it at all, I have only managed to produce chlorine. I have also another question about chlorine, what are those tablets made of for the swimming pool? They say they are chlorine tablets but i am not sure. (thought pure chlorine only comes in gas form). I wonder if one could use them to regenerate the bath, what i notice when i have too high a current is that the chlorine gas produced clearly regenerates the etchant in the surroundings of the carbon electrodes as it turns a lighter color. I will try to optimize the process further but if it does not improove i will just stick with H2O2.... ST
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[Homebrew_PCBs] Electrolytic regeneration of CuCl
2004-04-22 by Stefan Trethan
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