I've wondered about this, too, and I've read a few things "somewhere" - i.e. I can't actually swear they're true, but they seem to add up: Ammonium Persulphate as-is is a mild fertiliser without much toxicity. Once copper is dissolved in it, we get Copper Sulphate which is a little more toxic. This should be evaporated and disposed of in your local hazardous waste facility - you evaporate because at "non-hobby" quantities, you pay by weight. However, CuSO4 is also commonly used as a pool fungicide (algicide?), so folks with pools often just throw it in there - i.e. it's not that toxic to humans. Now, the following I do have evidence for: Looks like the original poster is in Australia, as I am. At least in NSW you can dispose of "hobby chemicals" for free on special days which rotate around the local councils: http://www.environment.nsw.gov.au/households/CleanoutGuide.htm When I eventually turn all of my jar of Ammonium Persulphate into blue salt, that's where I'll be heading, but it will be years! PG On Mon, Dec 7, 2009 at 1:34 PM, <tim.wade@...> wrote: > > > Read somewhere - can't find it now of course - that you should let it > evaporate so that you effectively end up with copper sulphate crystals > then place sealed bottle and put in the rubbish... > > From: Homebrew_PCBs@yahoogroups.com <Homebrew_PCBs%40yahoogroups.com> > [mailto:Homebrew_PCBs@yahoogroups.com <Homebrew_PCBs%40yahoogroups.com>] > On Behalf Of Stefan Trethan > Sent: Monday, 7 December 2009 1:11 AM > > To: Homebrew_PCBs@yahoogroups.com <Homebrew_PCBs%40yahoogroups.com> > Subject: Re: [Homebrew_PCBs] Ammonium Persulfate - poisonous? > > > On it's own it's Xn rating, no idea what it would be with the copper. > Anyway Xn is enough that you want to read the MSDS. > > <http://www.hillbrothers.com/msds/pdf/n/ammonium-persulfate.pdf> > > Which is not too bad, seems it's just barely Xn. > > Once you add the copper, you are not supposed to flush it down the > drain anyway, so it doesn't really matter if AP could be disposed of > that way. Bring it to your local waste disposal facility, in most > places around the world household hazardous waste can be brought in > free of charge, to discourage people dumping it illegally. > > ST > > On Sun, Dec 6, 2009 at 3:54 PM, Anthony Shipman <als@...<als%40iinet.net.au> > <mailto:als%40iinet.net.au <als%2540iinet.net.au>> > wrote: > > On Sun, 6 Dec 2009 06:45:22 am designer_craig wrote: > >> I am not sure if you mean Ammonium Peroxide or Ammonium Persulfate > but I > >> had some quantity of the latter sitting around for 15 years and it > all went > >> bad and would not etch anything when I tried to etch a board. Not > sure > >> what it decomposed to but I suspect it reverted to Ammonium Sulphate. > >> > >> Craig > > > > BTW how toxic is this stuff (Ammonium Persulfate). The container had > no > > warnings on it. I have some etchant with dissolved copper in it. Is it > > poisonous? What is the best way to dispose of it? > > > > -- > > Anthony Shipman Mamas don't let your babies > > als@... <als%40iinet.net.au> <mailto:als%40iinet.net.au<als%2540iinet.net.au>> > grow > > up to be outsourced. > > > > > > ------------------------------------ > > > > Be sure to visit the group home and check for new Links, Files, and > Photos: > > http://groups.yahoo.com/group/Homebrew_PCBsYahoo! Groups Links > > > > > > > > > > [Non-text portions of this message have been removed] > > > [Non-text portions of this message have been removed]
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Re: [Homebrew_PCBs] Ammonium Persulfate - poisonous?
2009-12-07 by Piers Goodhew
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