"perri.anthony" <perri.anthony@...> writes: > So I mixed a solution of Muriatic Acid (1/2 cup) & Hydrogen Peroxide (1 > Cup) to etch a board. It worked very well but now I am trying to figure > our how much baking soda it would take to neutralize that solution so it > can be safely disposed of. A couple of things... First, don't! Keep the solution around and use it for other boards. Eventually it will turn a dark green and become copper chloride etchant, which doesn't "expire". Note that this works if you're going to do it soon, else the peroxide breaks down and etching takes a lot longer. If you leave it as-is for a while and want to re-use it, just add a little more acid and peroxide to "charge" it again. Once there's enough copper in solution, you can recharge (regenerate) it with an air bubbler, then it's good pretty much forever. Alternatively, add a bunch of copper to it now just to convert it. I think I figured a half pound of copper per liter of HCl - you want the specific gravity (density) of the solution up to at least 1.2 for CuCl etchant (for details, see Adam's page at: http://members.optusnet.com.au/~eseychell/PCB/etching_CuCl/) Second, the copper in solution acts as a pH guide. It's green/brown in solution, but once the pH rises above 7 it precipitates out as a white milky fog. This assumes you have enough in solution to see the change, though.
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Re: [Homebrew_PCBs] Neutralizing Muriatic Acid & Hydrogen Peroxide
2009-05-21 by DJ Delorie
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