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Message

Re: Oh no, blank fibreglass again!

2003-04-26 by Max Davies

Liam/Tom/Mike

Thanks all for your suggestions.  It sounds as if there are several 
routes I could go from here.

Liam - your suggestion of a different type of etchant sounds like an 
obvious one to try.  I see you're UK based - can you direct me to a 
UK supplier of this etchant and I'll give it a go.  In fact my 
process is an industrial one (www.vantage.co.uk) - I have tried to 
stick with just one supplier to have half a chance of making it work!

Tom - It is electro-tin (I tried immersion tin before, and quickly 
realized the limitations!)  The surface is matt by design - does 
that sound like white tin?  In fact, since my post, I have managed 
to get a persistent coating, but it has required a *ridiculous* 
thickness of tin - a step of some 100 microns, and of course with an 
appalling surface topology.  It should definitely require less than 
this!

I didn't know you could plate solder - I'd always seen solder as a 
substance to be applied molten (therefore melting the resist).  It's 
definitely an avenue to look into if I remain unsuccessful with the 
tin.

My catalyst is indeed Palladium based.  Your suggestion of missing 
out the e/less copper is alluring - the fewer baths the better.  How 
does this work?

Thanks again all.  Max.

--- In Homebrew_PCBs@yahoogroups.com, "Mike Putnam" <circuit@g...> 
wrote:
> I have to differ with you, Tom. I used Tin Plate (Electrolysis) in 
my shop
> for many years and not Gold. Gold plating was too expensive. I 
etched with
> Ferric Chloride with no problems ever. Perhaps the trick is in how 
fast you
> are able to etch the panel.
> -Mike
> 
> ----- Original Message -----
> From: "twb8899" <twb8899@y...>
> To: <Homebrew_PCBs@yahoogroups.com>
> Sent: Saturday, April 26, 2003 11:40 AM
> Subject: [Homebrew_PCBs] Re: Oh no, blank fibreglass again!
> 
> 
> > Max,
> >
> > We always used solder plating as a resist and it worked fine. 
After
> > etching either reflow the solder or strip it off and apply one 
of the
> > newer "white tin" coatings if you want tin plating. Are you using
> > immersion tin or really electroplating it? Immersion tin is 
worthless
> > as a metallic resist but some electroplated tins will work if 
they
> > are plated heavy enough. By switching to solder plating you will
> > eliminate the problem. The same plating bath can probably be 
used.
> >
> > Ferric chloride will not work unless gold is being used as the 
etch
> > resist. Sulfuric/peroxide will work as an etchant for solder 
plated
> > boards. After stripping the photoresist dip the panel in a 10%
> > peroxide dip and then etch. This keeps the black crud from 
forming on
> > the solder plated surface for a better reflow finish. After 
etching
> > dip the panels in a 10% hydrochloric acid dip for about five 
minutes
> > to brighten the solder plating for reflow. Skip the peroxide and
> > hydrochloric dips if the solder is being stripped after etching. 
They
> > are only required for solder reflow quality.
> >
> > Bake the boards for at least 30 minutes at 300 degrees F after
> > etching and before reflowing. This is for outgassing any trapped
> > moisture and will keep the plated through holes from blowing out 
when
> > soldering.
> >
> > BTW, are you using the newer activated palladium cataylyst and
> > skipping the electroless copper stage?  Good luck on your new 
system!
> >
> > Tom
> >
> >
> > --- In Homebrew_PCBs@yahoogroups.com, "Max Davies" 
<max.davies@b...>
> > wrote:
> > > Hi everyone.
> > >
> > > A newbie to this group, I am (perhaps over-ambitiously) 
attempting
> > > to set up a micro through-hole plating line at home.  It's a 
lot
> > > more involved than I ever thought it would be, but I now have 
most
> > > of it working fine.  ...Except what should be the easy bit - 
the
> > > final stage - the etching!
> > >
> > >
> > > To give a brief description of what I do...
> > >
> > > STAGE 1:  Starting with plain, copper-clad board, I do the 
drilling.
> > > STAGE 2:  Apply photopolymer laminate, then expose & develop. 
(This
> > > is positive photopolymer, so the copper which will ultimately
> > become
> > > tracks is exposed to the air on developing the pattern)
> > > STAGE 3:  Go through a 6-stage process to electroless-plate the
> > > entire thing (including the holes & edges). The copper cover it
> > puts
> > > on is pretty thin, but uniform at 1-2 microns.
> > > STAGE 4:  Electroplate the copper - this gives reasonable 
thickness
> > > to the copper applied in stage 3 - I aim for 25 microns.
> > > STAGE 5:  Electroplate with tin to 10 microns.  This
> > > (theoretically!) protects the copper from etchant.
> > > STAGE 6:  Remove remaining resist.  Then etch.  This should 
leave
> > > the tin-plated areas untouched, everything else should be 
zapped.
> > >
> > >
> > > But alas no!  Stage 6 fails, because both tin *and* copper are
> > > etched, leaving me with a fine, blank piece of fibreglass!  It
> > > matters not whether I use Ferric Chloride or Sulphuric/Peroxide
> > > etchant - they both destroy what has been so lovingly 
created!!  So
> > > I reckon there must be something awry with my tin plating.
> > >
> > > It's a total impasse, and nothing I do, from 
increasing/decreasing
> > > current to re-formulating the tin plating bath according to
> > > manufacturer's instructions seems to change things.
> > >
> > > Does anyone else use a similar process, or have any clue about 
what
> > > might be the problem here?
> > >
> > > Max.
> >
> >
> >
> > Be sure to visit the group home and check for new Bookmarks and 
files:
> > http://groups.yahoo.com/group/Homebrew_PCBs
> >
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> >
> >
> >
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> >
> >

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