Adam Seychell wrote: > > rolanyang wrote: > >>Do you have a digital camera? Can you take a photo >>of your solution? When you have something that looks >>like http://www.techfreakz.org/cucl2/?slide=5 >>the solution is probably right. >> >>If you're getting brown or sludge, then first bubble >>air through it or add H2O2. If that doesnt help, then >>start adding HCl until it turns blue-greenish. >> >>Adding too much HCl won't slow down the reaction >>but not having enough CuCl2 will. >> >>Here's another idea: >>does anyone know if copper powder is cheap? >>The reaction would likely go a lot faster >>since the suface area of powder is drastically >>greater than when using plain old scrap wire >>or boards. >> > > You can get copper powder from some art supplies, but its VERY > expensive for what we are doing. I think they use it as pigments > in paint, or coating surfaces. Its almost fine as flour and thus > dangerous to breath in. > > You can react either, copper carbonate, copper(II) oxide (black > pigment powder) or copper(II) hydroxide (bright blue powder for > fungicides) with HCl and instantly get copper(II) chloride > solution. The problem is none of these are easily/cheaply > available as scrap copper in the quantities we need (1 kg of > copper). Maybe they are, but I don't know of any. > You can get few hundred grams at very high $/kg or buy 25 kg bag > from an industrial supplier at low $/kg but you'll have *way* to > much. Unfortunately there is no in-between. > > I'm going to have a better play around with getting copper metal > to react with HCl and do it fast as possible. I bet it's been tried, but does this work: CuSO4 + 2HCl -> CuCl2 + H2SO4 CuSO4 is in garden shops.
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Re: [Homebrew_PCBs] Re: HCl and H2O2 versus CuCl
2003-04-16 by Russell Shaw
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