Stefan Trethan wrote: > I see... > > Thanks for the explaination. > I already had the idea that basically the same might happen after writing the post. > > But i don't fully understand why all of these 3 parameters must be adjusted. > I only adjust one, the color. If to brown it doesn't work and H2O2 (obviously regeneration) is added. > Color is a good way of checking if too much cuprous ions are presents. Cuprous is not very soluble and will form film on copper being etched and slow down the reaction. a hydrometer is very easy and quick way of knowing when too much copper has been dissolved and water must be added. I think a copper content of 150 to 200g/l is ok. > The density: I don't monitor at all. But my H2O2 and HCl guide did say if there is any brown mud > settling on the bottom simply filter it through filter paper to get it out. > from the page you mentioned: "Etch rate will slow down and sludge may form with increasing density" - > has this experienced one of you? is this really happening? > Is the homebrew Hydrometer enough for normal work? but how to start if not bying the cucl but rather > starting with etching solid copper (or using my now in use fluid)? How exact has this to be? > Isn't there another method of getting the copper out (electrolytic deposition?)? > > Acid concentration: > I also don't monitor it, but it is too high, get fumes i think. > I don't like the titration, i don't like buying a buret and a stirrer and indicator etc. > But i believe this is quite important if bubbling... > From what I've been told, the free acid of commercial cupric chloride etchers can range from zero to 15% (wt). The acid doesn't have a large effect on etch rate, but for bubble etchers it should not be zero. Say 0.5% to 2% > > Also if only 3% HCl: > > Don't you get a lot of fumes from bubbling attacking any nearby oxidizeable material? > no, at 2% acid there isn't any problems. Adam
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Re: [Homebrew_PCBs] HCl and H2O2 versus CuCl
2003-04-13 by adam Seychell
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