I have used the Sulfamic acid, Thiourea, and stannous chloride since 1973 to tin plate boards.
If you are having problems, make sure your chemicals he correct ones and fresh. You need Tin(II) chloride SNCl2 CAS 7772-99-8, Thiourea SC(NH2)2 CAS 62-56-6 and Sulfamic Acid H3NSO3 CAS 5329-14-6
Formula for various batch sizes:
100 mL 50 mL 25 mL
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.5g Stannous Chloride 250mg 125 mg
2.0g Thiourea 1g 500 mg
3.0g Sulfamic Acid 1.5g 750 mg
100.0 mL Distilled water 50ml 25ml
Use a fresh batch each time the stuff doesn't last more than a day or so. Heat to 80 to 120 degrees and make sure you copper board is very clean and bright.
Read the MDS for the chemicals especially Thiourea it has health risks and is fairly nasty.
Craig