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Subject: Re: [Homebrew_PCBs] Re: Plated through holes and rinsing ?

From: Adam Seychell <adam_seychell@...>
Date: 2003-11-02

Markus Zingg wrote:
>>Hi Markus
>>
>>Question why are the anodes on your pics covert with clothes!
>> next the heated tanks do they have air agitation otherwise it get a
>>more hot to the element as eslewere in the tank!
>
>
> Uh, yes, I forgot to answer this part. They are here to keep small
> copper wires that will be created by the process away from the PCB
> where they obviousely could create short cuts. For a homebrew station
> - due to the smaller number of runs - maybe not that much of an issue,
> but they were part of the anode package as I bought it.
>
What small copper wires are you talking about ? I thought
the anode and cathode (PCB) are well separated so there
cannot be any possibility of contact.

Anode bags are very often used in many types of plating
baths. I know that for bright acid copper sulfate plating
the bags are used to inhibit solution flow around the anode
surface and preserve the black (or dark brown) film that
normally forms. I am using Macuspec 9241 brightener from
Macdermid and the data sheet stresses that anode bags must
be used. Well, since it didn't give any reasons why anode
bags must be used I didn't believe it and so I didn't use
any. Hmmm, yep, I soon learned why the bags are important.
The black film on anodes that's formed during plating is
very fragile and may easily strip off with air bubble
agitation. In these conditions the film is continuously
forming and releasing into the solution. After plating just
one PCB I could see enough precipitate produced that the
bottom of the tank was covered with a dark powder. I
installed the proper anode bags and it solved the problem
totally. I later read in plating books that the anode film
in bright acid copper plating is important for correct
dissolution of the anode.

Interesting , originally when I was plating with no
additives (200g/L H2S04 , 75g/L CuS04.5H20), the anodes
would not form this dark brown film, and would be more
stable. But there were still some anode film and small
amount of copper powder would release into the bath.

I also found that plating with low acid high copper
(75g/L H2S04 , 200g/L CuS04.5H20) then anodes dissolve much
cleaner and remain pink, but of course this bath has
terrible plating uniformity and is why no one uses it to
plate PCBs.

The anode bags are normally polypropylene fabric, that looks
very much like white denim. You could probably use 2 or 3
layers of 100% polyester fabric. I would first put it in
some 200g/L sulfuric acid for a week so that any thing in it
that might react with the acid will do so before in goes
into your plating tank.